Cleavage of Tellurium-Carbon Bonds of Hexavalent Organotellurium Compounds by Potassium Graphite

Author(s):  
Masataka Miyasato ◽  
Mao Minoura ◽  
Kin-ya Akiba
2004 ◽  
Vol 10 (10) ◽  
pp. 2590-2600 ◽  
Author(s):  
Masataka Miyasato ◽  
Takao Sagami ◽  
Mao Minoura ◽  
Yohsuke Yamamoto ◽  
Kin-ya Akiba

2017 ◽  
Vol 15 (10) ◽  
pp. 2163-2167 ◽  
Author(s):  
Zhouting Rong ◽  
Antonio M. Echavarren

The polycyclisation of polyeneynes catalyzed by gold(i) has been extended for the first time to the simultaneous formation of up to four carbon–carbon bonds, leading to steroid-like molecules with high stereoselectivity in a single step with low catalyst loadings.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Muhammad Irfan ◽  
Rabia Rehman ◽  
Mohd. R. Razali ◽  
Muhammad Adnan Iqbal ◽  
◽  
...  

AbstractIn wake of emerging applications of organotellurium compounds in biological and material science avenues, the current review describes their key synthetic methodologies while focusing the synthesis of organotellurium compounds through five ligand-to-metal linkages including carbon; carbon-oxygen; carbon-nitrogen; carbon-metal; carbon-sulfur to tellurium. In all of these linkages whether tellurium links with ligands through a complicated or simple pathways, it is often governed through electrophilic substitution reactions. The present study encompasses these major synthetic routes so as to acquire comprehensive understanding of synthetic organotellurium compounds.


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